Tuesday, October 22, 2019

1. Real Numbers

Exercise 1.2
Class X

Q.No. 1. Express each number as a product of its prime factors:
(i) 140 (ii) 156 (iii) 3825 (iv) 5005 (v) 7429
Solution:
(i)                 140
Prime factors of 140 = 2x2x5x7 Ans.
(ii)               156
Prime factors of 156 = 2x2x3x13 Ans.
(iii)             3825
Prime factors of 3825 = 3x3x5x5x17 Ans.
(iv)             5005
Prime factors of 5005 = 5x7x11x13 Ans.
(v)               7429
Prime factors of 7429 = 17x19x23 Ans.

Q.No. 2. Find the LCM and HCF of the following pairs of integers and verify that LCMxHCF = Product of the two numbers.
(i) 26 and 91 (ii) 510 and 92 (iii) 336 and 54

Solution:
(i)                 26 and 91
Prime factors of 26 = 2x13
Prime factors of 91 = 13x7
LCM = 2x7x13 = 182
HCF = 13
LCM x HCF = 182x13=2366
Product of number = 26x91 = 2366
LCMxHCF = Product of number is verified.
(ii)               510 and 92
Prime factors of 510 = 2x3x5x17
Prime factors of 92 = 2x2x23
LCM = 2x2x3x5x17x23 = 23460
HCF = 2
LCMxHCF = 23460x2 = 46920
Product of number = 46920
Hence, LCMxHCF = Product of number is verified.
(iii)             336 and 54
Prime factors of 336 = 2x2x2x2x3x7
Prime factors of 54 = 2x3x3x3
LCM = 2x2x2x2x3x3x3x7 = 3024
HCF = 2x3 = 6
LCMxHCF = 18144
Product of number = 336x54 = 18144
Hence, LCMxHCF = Product of number is verified.

Q.No. 3. Find the LCM and HCF of the following integers by applying the prime factorisation method.
(i) 12, 15and 21 (ii) 17, 23 and 29 (iii) 8,9 and 25

Solution:
(i)                 12, 15 and 21
Prime factorisation of 12 = 2x2x3
Prime factorisation of 15 = 3x5
Prime factorisation of 21 = 3x7
LCM = 2x2x3x5x7 = 420
HCF = 3
(ii)               17, 23 and 29
Prime factorisation of 17 = 17
Prime factorisation of 23 = 23
Prime factorisation of 29 = 29
LCM = 17x23x29 = 11339
HCF = 1

(iii)             8, 9 and 25
Prime factorisation of 8 = 2x2x2 = 8
Prime factorisation of 9 = 3x3
Prime factorisation of 25 = 5x5
LCM = 2x2x2x3x3x5x5 = 1800
HCF = 1

Q.No. 4.Given that HCF (306, 657) = 9 , find LCM (306, 657)

Solution:
LCMxHCF = Product of numbers
or, LCM = Product of numbers/HCF
or, LCM = 306x657/9
or, LCM = 22338 Ans.

Q.No. 5. Check whether  can end with the digit 0 for any natural number n.

Solution:
Prime factorisation of 6 = 2x3
So, the prime factorisation of 6 is not divisible by 5.
Hence, cannot end with 0 for any natural number n according to Fundamental Theorem of Arithmetic.

Q.No. 6. Explain why 7x11x13 + 13 and 7x6x5x4x3x2x1 + 5 are composite numbers.
Solution:
These numbers can be expressed as the form of the factorisation of prime numbers.
So, these numbers are composite numbers.

Q.No. 7. There is circular path around a sports field. Sonia takes 18 minutes to drive one round of the field. while Ravi takes 12 minutes for the same. Suppose they both start at the same point and at the same time, and go the same direction. After how many minutes will they meet again at the starting point.
Solution:
Prime factorisation of 18 = 2x3x3
Prime factorisation of 18 = 2x2x3x3
LCM of 12 and 18 = 2x2x3x3 = 36
So, they will meet again after 36 minutes. Ans.

Saturday, October 12, 2019

1. Real Numbers

Class X

NCERT Text Book Solution

Exercise 1.1

1. Use Euclid's division algorithm to find the HCF of 
(i)135 and 225 (ii) 196 and 38220 (iii) 867 and 255

Solution:
(i)
From question it is clear that
225 > 135.
Apply Euclid's division lemma, to 135 and 225.
225 = 135x1 + 90
135 = 90x1 + 45
90 = 45x2 + 0
The remainder has now become zero.
The HCF of 225 and 135 is 45 Ans.

(ii)
From question it is clear that 
38220>196
Apply Euclid's division lemma, to 38220 and 196.
38220 = 196x195 + 0
The remainder has now become zero.
The HCF of 38220 and 196 is 195 Ans.

(iii)
From question it is clear that
867>255
Apply Euclid's division lemma, to 867 and 255.
867 = 255x3 + 102
255 = 102x2 + 51
102 = 51x2 + 0 
The remainder has now become zero.
The HCF of 867 and 255 is 51 Ans

2. Show that any positive odd integer is of the form 6q + 1, or 6q + 3, or 6q + 5, where q is some integer.

Solution:

Let a be any positive integer and b = 6.
Now, by Euclid's division algorithm,
a = 6q + r for some integer q ≥ 0,
r = 0, 1, 2, 3, 4, 5
Because 0 ≤ r < b
So, a can be
6q,or 6q + 1, or 6q + 2, or 6q + 3, or 6q + 4, or 6q + 5.
Since a is odd, a cannot be 6q, or 6q + 2, or 6q + 4 ( since they are all divisible by 2)
Therefore, any positive odd integer is of the form 6q + 1, or 6q + 3, or 6q + 5. Proved.

3. An army contingent of 616 members is to march behind an army band of 32 members in a parade. The two groups are to march in the same number of columns. What is the maximum number of columns in which they can march ?

Solution:
For this, it will be find out the HCF of 616 and 32.
Apply Euclid's algorithm, to 616 and 32.
616 = 32x19 + 8
32 = 8x4 + 0
So, the HCF of 616 and 32 is 8.
Therefore, the maximum number of columns in which they can march = 8 Ans.

4. Use Euclid's division lemma to show that the square of any positive integer is either of the form 3m, or 3m + 1 for some integer m.

Solution:
Let a be any positive integer and b = 3.
Now, Euclid's division lemma,
a = 3q + r for some integer q ≥ 0,
Since, 0 ≤ r < 3
a can be 3q, or 3q + 1, or 3q + 2

Therefore,
a² = 9q², or 9q² + 6q + 1, or 9q² + 12q + 1.
or, a² = 3x3q², or 3( 3q² + 2q) + 1, or 3(3q² + 4q) + 1
So, the square of any positive integer is either of the form 3m, or 3m + 1. Proved

5. Use Euclid's division lemma to show that the cube of any positive integer is of the form 9m, 9m + 1 or 9m + 8.

Solution:

Let a be any positive integer and b = 9.
Now, Euclid's division lemma,
a = 9q + r for some integer q ≥ 0,
Since, 0 ≤ r < 9
a can be 9q, or 9q + 1, or 9q + 2, 9q + 3, or ...... 9q + 8.

Therefore,
a³ = 9x81q³, or 9(81q³ + 27q² + 3q)+ 1, or 9(81q³ + 54q² + 6q) + 8 ..................
So, the cube of any positive integer is of the form 9m,or 9m + 1 or 9m + 8. Proved.

4.7 Ampere's Circuital Law

Subject: Physics

Class XII

Chapter: 4. Moving Charges and Magnetism


Ampere's Law
 "The integral of magnetic field around a closed path is equal to the product of absolute permeability and total current passing through it."

Mathematical form
∮B.dl = μ₀.I

Here,
B = Magnetic field
dl = Current element
μ₀ = Absolute Permeability
I = Current passing through it

Proof
Consider about an infinitesimal carrying conductor through which I current passing is passing. Magnetic field lines are produced around the conductor as the form of concentric circles.
Magnetic field at a distance due to this infinitesimal conductor. 
B = μ₀.2I/4πa ................... (i)

Now consider about a circle of radius a having a current element dl.
Both B and dl have same direction because B is along the the tangent of circle.
Hence,
B.dl = Bdlcosθ = Bdlcos0⁰ = Bdl

Now integrate the closed path
∮B.dl = ∮Bdl .............. (ii)
Now putting the value of B
∮B.dl = μ₀.2Idl/4πa
∮B.dl  = μ₀.2I/4πa∮dl
For complete cirecle
∮dl = 2πa
∮B.dl  = μ₀.2I.2πa/4πa
∮B.dl = μ₀.I
Proved

Friday, October 11, 2019

4.6 Magnetic Field on the Axis of Circular Current Loop

Subject: Physics

Class : XII

Chapter 4. Moving Charges and Magnetism

4.6 Magnetic Field on the Axis of Circular Current Loop




















Consider about a circular loop of radius R carrying the current I. The loop is placed in the y-z plane with its centre at the origin O. The x axis is the axis of the loop. There is a point P at a distance x from the centre of the loop at which magnetic field is to be determined.

Mathematical Calculation

dl is the conducting element of the loop.
The magnitude of dB of the magnetic field due to dl is according to Biot-Savart Law
dB = 𝝁₀I|dlxr|/4𝜋r³
Now 
r² = x² + R²
Any element to loop will be perpendicular to the displacement vector r from dl to the axial point P is in the x-y plane.
Hence,
|dlxr| = rdl
dB = 𝝁₀Idlr/4𝜋r³ ............... (i)
Now putting the value of r
dB = 𝝁₀Idl/4𝜋(x² + R²)
The direction of dB is perpendicular to the plane formed by dl and r.
It has an x- component dBₓ and a component perpendicular to x-axis dB⫡.
When the components perpendicular to the x- axis are summed over, they cancel out.
Only the x component survives.
dBₓ = dBcos𝜃
From figure 
cos𝜃 = R/√(x² + R²) ............. (ii)
Now from eqn. no. (i) and (ii)
dBₓ = 𝝁₀IdlR/4𝜋(x² + R²)³/²
For whole circular loop
dl = 2𝜋R
Magnetic field at P due to entire circular loop
= B = Bₓi = 𝝁₀IR²/2𝜋(x² + R²)³/²i
Field at the centre of the loop. Here x = 0
B₀ = 𝝁₀I/2R

The direction of the magnetic field is determined by the help of 
Fleming Right Hand Thumb rule.

Monday, October 7, 2019

11. Alcohols, Phenols and Ethers

Alcohols, Phenols and Ethers

Class XII
Subject : Chemistry

Alcohols

Alcohols are compounds in which a hydroxyl(-OH) group attached to the saturated carbon atom.
General formula of alcohol - R-OH
The hydroxyl group is the functional group of alcohols.

Alcohols containing one hydroxyl are called Monohydric Alcohols.
Alcohols with two, three, or more hydroxyl groups are known as Dihydric Alcohols, Trihydric Alcohols, and Polyhydric Alcohols respectively.
For example,


Primary, Secondary and Tertiary Alcohols

Monohydric alcohols are classified as primary, secondary or tertiary depending upon whether the -OH group is attached to primary, secondary or a tertiary carbon.


Structure

Consider about the structure of Methyl Alcohol (CH₃OH). In methyl alcohol both oxygen and carbon are sp³ hybridized. Two of the sp³ orbitals of oxygen are completely filled and cannot take part in bond formation.

The C-O bond methyl alcohol is formed by overlap of an sp³ orbital of carbon and an sp³ orbital of oxygen. The O-H bond is formed by overlap of an sp³ orbital of oxygen and s orbital of hydrogen. The C-O-H bond angle is 105⁰. It is less than the normal tetrahedral angle. This is because the two completely filled sp³ orbitals of oxygen repel each other. This result in reduction of the bond angle.

Structure of Methyl Alcohol is given below



















Continue ................ 

Saturday, October 5, 2019

4.4.2 Cyclotron Class XII.

The Cyclotron is a machine which is used to accelerate the charged particles.
This machine was invented by E.O. Lowrence and M.S Livingston. 

Construction

It has two hollow chambers of D shaped is called dees. There is some gap between the dees in which source of positive particles are kept. These dees are connected by high frequent oscillator which provides high frequent electric field between the gap of dees. This machine is placed between the two powerful electromagnetic poles.

Working Principle

Positive charged particles accelerated from D1 to D2 when D1 and D2 are positive and negative respectively. In D2 charged particles accelerated perpendicular to the magnetic field.

The schematic figure of Cyclotron is drawn below.


The charged particles move in a semi circular path perpendicular to the magnetic field.
Let the time taken to complete one revolution is T.
T = 2πm/qB
Frequency = 1/T
= qB/2πm
During the circular motion of charged particles.
mv²/r = qvB
v = qBr/m

Kinetic Energy = mv²/2
Now, putting the value of v.
Kinetic Energy = q²B²r²/2m.
Time of revolution is independent of speed of particles and radius of trajectory.

Uses of Cyclotron are as follow

1. Uses in the nuclear reactor plant
2. To implant ions into solids
3. To synthesis materials
4. To produce radio active substances in the hospital.

Friday, October 4, 2019

3. Atoms and Molecules IX Chapter 3

Page 32

Q.No. 1:

In a reaction 5.3 g of sodium carbonate reacted with 6 g of ethanoic acid. The products were 2.2 g
of carbon dioxide, 0.9g water and 8.2 g of sodium ethanoate. Show that these observations are in
agreement with the law of conservation of mass.
Sodium carbonate + ethanoic acid → sodium ethanoate + carbon dioxide + water

Answer:

In a reaction, sodium carbonate reacts with ethanoic acid to produce sodium ethanoate,
carbondioxide, and water.
 Sodium + Ethanoic → Sodium + Carbon + Water
Carbonate acid ethanoate dioxide

Mass of sodium carbonate = 5.3g (Given)
Mass of ethanoic acid = 6g (Given)
Mass of sodium ethanoate = 8.2g (Given)
Mass of carbon dioxide = 2.2 (Given)
Mass of water = 0.9g (Given)
Now, total mass before the reaction = (5.3 + 6)g
= 11. 3g
and total mass after the reaction = (8.2 + 2.2 + 0.9)g
= 11.3g
Therefore, Total mass before the reaction = Total mass after the reaction
Hence, the given observations are in agreement with the law of conservation of ma

Page 33
Q.No. 2:

Hydrogen and oxygen combine in the ratio of 1 : 8 by mass to form water. What mass of oxygen
gas would be required to react completely with 3g of hydrogen gas?

Answer:

It is given that the ratio of hydrogen and oxygen by mass to form water is 1:8. Then, the mass of
oxygen gas required to react completely with 1g of hydrogen gas is 8g. Therefore, the mass of
oxygen gas required to react completely with 3g of hydrogen gas is 8 × 3g = 24 g.

Q.No. 3:

Which postulate of Dalton's atomic theory is the result of the law of conservation of mass?

Answer:

The postulate of Dalton's atomic theory which is a result of the law of conservation of mass is
“Atoms are indivisible particles, which can neither be created nor destroyed in a chemical
reaction”.

Q.No. 4:

Which postulate of Dalton's atomic theory can explain the law of definite proportions?

Answer:

The postulate of Dalton's atomic theory which can explain the law of definite proportion is “The
relative number and kind of atoms in a given compound remains constant”.

Page 35
Q.No. 1:

Define atomic mass unit.

Answer:

Mass unit equal to exactly one- twelfth the mass of one atom of carbon - 12 is called one atomic
mass unit. It is written as 'u'.

Q.No. 2:

Why is it not possible to see an atom with naked eyes?

Answer:

The size of an atom is so small that it is not possible to see it with naked eyes. Also, atom of an
element does not exist independently.

Page 39

Q.No. 1:

Write down the formula of
(i) sodium oxide
(ii) aluminium chloride
(iii) sodium suphide
(iv) magnesium hydroxide

Answer:

(i) Sodium oxide → Na2O
(ii) Aluminium chloride → AlCl3
(iii) Sodium suphide → Na2S
(iv) Magnesium hydroxide → Mg(OH)2

Q.No. 2:

Write down the names of compounds represented by the following formula:
(i) Al2(SO4)3
(ii) CaCl2
(iii) K2SO4
(iv) KNO3
(v) CaCO3

Answer:

(i) Al(SO4)3→ Aluminium sulphate
(ii) CaCl2→ Calcium chloride
(iii) K2SO4→ Potassium sulphate
(iv) CaCO3→ Calcium carbonate

Q.No. 3:

What is meant by the term chemical formula?

Answer:

The chemical formula of a compound means the symbolic representation of the composition of a
compound. From the chemical formula of a compound, we can know the number and kinds of
atoms of different elements that constitute the compound. For example, from the
chemical formula CO2 of carbon dioxide, we come to know that one carbon atom and two oxygen
atoms are chemically bonded together to form one molecule of the compound, carbon dioxide.

Question 4:

How many atoms are present in a
(i) H2S molecule and
(ii) PO4
3-
ion?

Answer :

(i) In an H2S molecule, three atoms are present; two of hydrogen and one of sulphur.
(ii) In a PO4
3-
ion, five atoms are present; one of phosphorus and four of oxygen.

Page 40

Question 1:

Calculate the molecular masses of H2, O2, Cl2, CO2, CH4, C2H6, C2H4, NH3, CH3OH.

Answer:

Molecular mass of H2 = 2 × Atomic mass of H
= 2 × 1 = 2u
Molecular mass of O2 = 2 × Atomic mass of O
= 2 × 16 = 32u
Molecular mass of Cl2 = 2 × Atomic mass of Cl
= 2 × 35.5 = 71 u
Molecular mass of CO2 = Atomic mass of C + 2 × Atomic mass of O
= 12 + 2 × 16 = 44 u
Molecular mass of CH4 = Atomic mass of C + 4 × Atomic mass of H
= 12 + 4 × 1 = 16 u
Molecular mass of C2H6 = 2 × Atomic mass of C + 6 × Atomic mass of H
= 2 × 12 + 6 × 1 = 30u
Molecular mass of C2H4 = 2 × Atomic mass of C + 4 × Atomic mass of H
= 2 × 12 + 4 × 1 = 28u
Molecular mass of NH3 = Atomic mass of N + 3 × Atomic mass of H
= 14 + 3 × 1 =17 u
Molecular mass of CH3OH Atomic mass of C+4 ×Atomic mass of H+Atomic mass of O
= 12 + 4 × 1 + 16 = 32 u

Q.No. 2:

Calculate the formula unit masses of ZnO, Na2O, K2CO3, given masses of Zn = 65u, Na = 23u, K
= 39u, C = 12u, and O = 16u.

Answer :
Formula unit mass of ZnO = Atomic mass of Zn + Atomic mass of O
= 65 + 16 = 81 u
Formula unit mass of Na2O = 2 × Atomic mass of Na + Atomic mass of O
= 2 × 23 + 16 = 62u
Formula unit mass of K2CO3
= 2 × Atomic mass of K + Atomic mass of C + 3 × Atomic mass of O
= 2 × 39 + 12 + 3 × 16 = 138u

Page 42

Question 1:
If one mole of carbon atoms weighs 12 gram, what is the mass (in gram) of 1 atom of carbon?

Answer:

One mole of carbon atoms weighs 12g (Given)
i.e., mass of 1 mole of carbon atoms = 12g
Then, mass of 6.022× 1023 number of carbon atoms = 12g
Therefore, mass of 1 atom of carbon =
12
6.022× 10– 23 g g
= 1.9926 × 10– 23 g

Q.No. 2:

Which has more number of atoms, 100 grams of sodium or 100 grams of iron (given, atomic mass
of Na = 23u, Fe =56 u)?

Answer 2:

Atomic mass of Na = 23u (Given)
Then, gram atomic mass of Na = 23g
Now, 23g of Na contains = 6.022×1023 number of atoms
Thus, 100g of Na contains =
6.022×1023 ×10⁻²³
number of atoms
= 2.6182 × 1024 number of atoms
Again, atomic mass of Fe = 56u (Given)
Then, gram atomic mass of Fe = 56g
Now, 56 g of Fe contains = 6.022×1023 number of atoms
Thus, 100 g of Fe 6.022×1023 ×100
56
number of atoms
= 1.0753 × 1024 number of atoms
Therefore, 100 grams of sodium contain more number of atoms than 100 grams of iron.

Q.No. 5:

Give the names of the elements present in the following compounds:
(a) Quick lime
(b) Hydrogen bromide
(c) Baking powder
(d) Potassium sulphate.

Answer:

Compound Chemical formula Elements present
Quick lime CaO Calcium, oxygen
Hydrogen bromide HBr Hydrogen, bromine
Baking powder NaHCO3 Sodium, hydrogen, carbon,
oxygen
Potassium sulphate K2SO4 Potassium, sulphur, oxygen

Q.No. 6:

Calculate the molar mass of the following substances:
(a) Ethyne, C2H2
(b) Sulphur molecule, S8
(c) Phosphorus molecule, P4 (atomic mass of phosphorus = 31)
(d) Hydrochloric acid, HCl
(e) Nitric acid, HNO3

Answer:

(a) Molar mass of ethyne, C2H2 = 2 × 12 + 2 × 1 = 28g
(b) Molar mass of sulphur molecule, S8 = 8 × 32 = 256g
(c) Molar mass of phosphorus molecule, P4 = 4 × 31 = 124g
(d) Molar mass of hydrochloric acid, HCl = 1 + 35.5 = 36.5g
(e) Molar mass of nitric acid, HNO3 = 1 + 14 + 3 × 16 = 63g

Q.No. 7:

What is the mass of
(a) 1 mole of nitrogen atoms?
(b) 4 mole of aluminium atoms (Atomic mass of aluminium = 27)?
(c) 10 moles of sodium sulphite (Na2SO3)?

Answer:

(a) The mass of 1 mole of nitrogen atoms is 14g.
(b) The mass of 4 moles of aluminium atoms is (4 × 27)g = 108g
(c) The mass of 10 moles of sodium sulphite (Na2SO3) is 10 × [2 × 23 + 32 + 3 × 16]g
= 10 × 126g = 1260g

Q.No. 8:

Convert into mole.
(a) 12g of oxygen gas
(b) 12g of water
(c) 22g of carbon dioxide

Answer:

(a) 32 g of oxygen gas = 1 mole
Then, 12g of oxygen gas = 12/32 mole = 0.375 mole
(b) 18g of water = 1 mole
Then, 20 g of water = 20/18 mole = 1.11 moles (approx.)
(c) 44g of carbon dioxide = 1 mole
Then, 22g of carbon dioxide = 22/44 mole = 0.5 mole

Q.No. 9:

What is the mass of:

(a) 0.2 mole of oxygen atoms?
(b) 0.5 mole of water molecules?

Answer:

(a) Mass of one mole of oxygen atoms = 16g
Then, mass of 0.2 mole of oxygen atoms = 0.2 × 16g = 3.2g
(b) Mass of one mole of water molecule = 18g
Then, mass of 0.5 mole of water molecules = 0.5 × 18g = 9g
Question 10:
Calculate the number of molecules of sulphur (S8) present in 16g of solid sulphur.
Answer 10:
 1 mole of solid sulphur (S8) = 8 × 32g = 256g
i.e., 256g of solid sulphur contains = 6.022 × 1023 molecules
Then, 16g of solid sulpur contains 6.022×1023
256
× 16 molecules
= 3.76 × 1022 molecules (approx)

Q.No. 11:

Calculate the number of aluminium ions present in 0.051g of aluminium oxide.
(Hint: The mass of an ion is the same as that of an atom of the same element. Atomic mass of Al
= 27u)

Answer:

1 mole of aluminium oxide (Al2O3) = 2 × 27 + 3 × 16 = 102g
i.e., 102g of Al2O3 = 6.022 × 10⁻²³ molecules of Al2O3
Then, 0.051 g of Al2O3 contains =
6.022 × 10⁻²³ 
102
× 0.051 molecules
= 3.011 × 1020
 molecules of Al2O3
The number of aluminium ions (Al3+
) present in one molecules of aluminium oxide is 2.
Therefore, The number of aluminium ions (Al3+
) present in
3.11 × 1020 molecules (0.051g) of aluminium oxide (Al2O3) = 2 × 3.011 × 1020
= 6.022 × 1020

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