Thursday, January 6, 2022

Electromagnetic Waves

Electromagnetic Spectrum


At the time Maxwell predicted the existence of electromagnetic waves, the only familiar electromagnetic waves were the visible light waves. The existence of ultraviolet and infrared waves was barely established. By the end of the nineteenth century, X-rays and gamma rays had also been discovered. We now know that, electromagnetic waves include visible light waves, X-rays, gamma rays, radio waves, microwaves, ultraviolet and infrared waves. The classification of em waves according to frequency is the electromagnetic spectrum. There is no sharp division between one kind of wave and the next. The classification is based roughly on how the waves are produced and/or detected.



(Figure The electromagnetic spectrum, with common names for various part of it. The various regions do not have sharply defined boundaries.)


We briefly describe these different types of electromagnetic waves, in order of decreasing wavelengths.


Radio waves


Radio waves are produced by the accelerated motion of charges in conducting wires. They are used in radio and television communication systems. They are generally in the frequency range from 500 kHz to about 1000 MHz. The AM (amplitude modulated) band is from 530 kHz to 1710 kHz. Higher frequencies upto 54 MHz are used for short wave bands. TV waves range from 54 MHz to 890 MHz. The FM (frequency modulated) radio band extends from 88 MHz to 108 MHz. Cellular phones use radio waves to transmit voice communication in the ultrahigh frequency (UHF) band. How these waves are transmitted and received is described in Chapter 15.



Microwaves


Microwaves (short-wavelength radio waves), with frequencies in the gigahertz (GHz) range, are produced by special vacuum tubes (called klystrons, magnetrons and Gunn diodes). Due to their short wavelengths, they are suitable for the radar systems used in aircraft navigation. Radar also provides the basis for the speed guns used to time fast balls, tennis- serves, and automobiles. Microwave ovens are an interesting domestic application of these waves. In such ovens, the frequency of the microwaves is selected to match the resonant frequency of water molecules so that energy from the waves is transferred efficiently to the kinetic energy of the molecules. This raises the temperature of any food containing water.


Microwave oven


The spectrum of electromagnetic radiation contains a part known as microwaves. These waves have frequency and energy smaller than visible light and wavelength larger than it. What is the principle of a microwave oven and how does it work?Our objective is to cook food or warm it up. All food items such as fruit, vegetables, meat, cereals, etc., contain water as a constituent. Now, what does it mean when we say that a certain object has become warmer? When the temperature of a body rises, the energy of the random motion of atoms and molecules increases and the molecules travel or vibrate or rotate with higher energies. The frequency of rotation of water molecules is about

2.45 gigahertz (GHz). If water receives microwaves of this frequency, its molecules absorb this radiation, which is equivalent to heating up water. These molecules share this energy with neighbouring food molecules, heating up the food.

One should use porcelain vessels and not metal containers in a microwave oven because of the danger of getting a shock from accumulated electric charges. Metals may also melt from heating. The porcelain container remains unaffected and cool, because its large molecules vibrate and rotate with much smaller frequencies, and thus cannot absorb microwaves. Hence, they do not get heated up.

Thus, the basic principle of a microwave oven is to generate microwave radiation of appropriate frequency in the working space of the oven where we keep food. This way energy is not wasted in heating up the vessel. In the conventional heating method, the vessel on the burner gets heated first, and then the food inside gets heated because of transfer of energy from the vessel. In the microwave oven, on the other hand, energy is directly delivered to water molecules which is shared by the entire food.



Infrared waves


Infrared waves are produced by hot bodies and molecules. This band lies adjacent to the low-frequency or long-wave length end of the visible spectrum. Infrared waves are sometimes referred to as heat waves. This is because water molecules present in most materials readily absorb infrared waves (many other molecules, for example, CO2, NH3, also absorb infrared waves). After absorption, their thermal motion increases, that is, they heat up and heat their surroundings. Infrared lamps are used in physical therapy. Infrared radiation also plays an important role in maintaining the earth’s warmth or average temperature through the greenhouse effect. Incoming visible light (which passes relatively easily through the atmosphere) is absorbed by the earth’s surface and re-radiated as infrared (longer wavelength) radiations. This radiation is trapped by greenhouse gases such as carbon dioxide and water vapour. Infrared detectors are used in Earth satellites, both for military purposes and to observe growth of crops. Electronic devices (for example semiconductor light emitting diodes) also emit infrared and are widely used in the remote switches of household electronic systems such as TV sets, video recorders and hi-fi system.


Visible rays


It is the most familiar form of electromagnetic waves. It is the part of the spectrum that is detected by the human eye. It runs from about 4 × 1014 Hz to about 7 × 1014 Hz or a wavelength range of about 700 – 400 nm. Visible light emitted or reflected from objects around us provides us information about the world. Our eyes are sensitive to this range of wavelengths. Different animals are sensitive to different range of wavelengths. For example, snakes can detect infrared waves, and the ‘visible’ range of many insects extends well into the utraviolet.



Ultraviolet rays


It covers wavelengths ranging from about 4 × 10‐⁷ m (400 nm) down to 6 × 10‐¹⁰m (0.6 nm). Ultraviolet (uv) radiation is produced by special lamps and very hot bodies. The sun is an important source of ultraviolet light. But fortunately, most of it is absorbed in the ozone layer in the atmosphere at an altitude of about 40 – 50 km. uv light in large quantities has harmful effects on humans. Exposure to UV radiation induces the production of more melanin, causing tanning of the skin. UV radiation is absorbed by ordinary glass. Hence, one cannot get tanned or sunburn through glass windows.

Welders wear special glass goggles or face masks with glass windows to protect their eyes from large amount of UV produced by welding arcs. Due to its shorter wavelengths, UV radiations can be focussed into very narrow beams for high precision applications such as LASIK (Laser-assisted in situ keratomileusis) eye surgery. UV lamps are used to kill germs in water purifiers. 

Ozone layer in the atmosphere plays a protective role, and hence its depletion by chlorofluorocarbons (CFCs) gas (such as freon) is a matter of international concern. 


X-rays


Beyond the uv region of the electromagnetic spectrum lies the x-ray region. We are familiar with x-rays because of its medical applications. It covers wavelengths from about 10‐⁸ m (10 nm) down to 10‐¹⁰ m 

(10‐⁴ nm). One common way to generate X-rays is to bombard a metal target by high energy electrons. X-rays are used as a diagnostic tool in medicine and as a treatment for certain forms of cancer. Because x-rays damage or destroy living tissues and organisms, care must be taken to avoid unnecessary or over exposure. 


Gamma rays


They lie in the upper frequency range of the electromagnetic spectrum and have wavelengths of from about 10‐¹⁰m to less than 10‐¹⁰m. This high frequency radiation is produced in nuclear reactions and 

also emitted by radioactive nuclei. They are used in medicine to destroy cancer cells. 

Table summarises different types of electromagnetic waves, their production and detections. As mentioned earlier, the demarcation between different regions is not sharp and there are overlaps.


Wednesday, December 29, 2021

Some Basic Concepts of Chemistry

  1. Some Basic Concepts of Chemistry

The study of chemistry is very important as its domain encompasses every sphere of life. Chemists study the properties and structure of substances and the changes undergone by them. All substances contain matter, which can exist in three states – solid, liquid or gas. The constituent particles are held in different ways in these states of matter and they exhibit their characteristic properties. 


Classification of Matter


Matter can also be classified into elements, compounds or mixtures. An element contains particles of only one type, which may be atoms or molecules. The compounds are formed where atoms of two or more elements combine in a fixed ratio to each other. Mixtures occur widely and many of the substances present around us are mixtures.

When the properties of a substance are studied, measurement is inherent. 


Measurements of Substances in SI System


The quantification of properties requires a system of measurement and units in which the quantities are to be expressed. Many systems of measurement exist, of which the English and the Metric Systems are widely used. The scientific community, however, has agreed to have a uniform and common system throughout the world, which is abbreviated as SI units (International System of Units).

Since measurements involve recording of data, which are always associated with a certain amount of uncertainty, the proper handling of data obtained by measuring the quantities is very important. The measurements of quantities in chemistry are spread over a wide range of 10-31 to 1023. Hence, a convenient system of expressing the numbers in scientific notation is used. The uncertainty is taken care of by specifying the number of significant figures, in which the observations are reported. The dimensional analysis helps to express the measured quantities in different systems of units. Hence, it is possible to interconvert the results from one system of units to another.


Basic Laws of Chemical Combination


The combination of different atoms is governed by basic laws of chemical combination — these being the 

1. Law of Conservation of Mass, 2. Law of Definite Proportions, 3. Law of Multiple Proportions, 

4. Gay Lussac’s Law of Gaseous Volumes and 5. Avogadro Law. 

All these laws led to the Dalton’s atomic theory, which states that atoms are building blocks of matter. 


Atomic and Molecular Mass


The atomic mass of an element is expressed relative to 12C isotope of carbon, which has an exact value of 12u. Usually, the atomic mass used for an element is the average atomic mass obtained by taking into account the natural abundance of different isotopes of that element. The molecular mass of a molecule is obtained by taking sum of the atomic masses of different atoms present in a molecule. The molecular formula can be calculated by determining the mass per cent of different elements present in a compound and its molecular mass.


Avogadro Number

 

The number of atoms, molecules or any other particles present in a given system are expressed in the terms of Avogadro constant (6.022 × 1023). This is known as 1 mol of the respective particles or entities.


Stoichiometric Calculations


Chemical reactions represent the chemical changes undergone by different elements and compounds. A balanced chemical equation provides a lot of information. The coefficients indicate the molar ratios and the respective number of particles taking part in a particular reaction. The quantitative study of the reactants required or the products formed is called stoichiometry. Using stoichiometric calculations, the amount of one or more reactant(s) required to produce a particular amount of product can be determined


The Amount of Substance in a Solution


The amount of substance present in a given volume of a solution is expressed in number of ways, e.g., 1. Mass Per cent, 2. Mole fraction, 3. Molarity and 4. Molality.

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